Free radical rearrangements of organocobaloximes: alkynyl to cycloalkylidene and hexenyl to cyclopentylmethyl

P Bougeard, CJ Cooksey, MD Johnson…

文献索引：Journal of Organometallic Chemistry, , vol. 288, p. 349 - 358

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被引用次数: 8

摘要

... Journal of Organometallic Chemistry. ... The rearrangements are rationalised in terms of a reversible homolysis of the carbon-cobalt bond, rearrangement of the organic radical and recapture by the cobalt(II) fragment to give complexes that are more stable to irradiation than their ...