Pd-catalyzed enantioselective aerobic oxidation of secondary alcohols: applications to the total synthesis of alkaloids

S Krishnan, JT Bagdanoff, DC Ebner…

文献索引：Bestmann, Hans Juergen; Woelfel, Gerhard Angewandte Chemie, 1984 , vol. 96, # 1 p. 52

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被引用次数: 106

摘要

... Volume: Page: ... application of a Pd-catalyzed oxidative kinetic resolution delivered enantioenriched diol (−)-12 in 96% ee and 37 ... removal of the tosyl group using tetrabutylammonium fluoride (TBAF)(32) then delivered (−)-aurantioclavine ((−)-1). figure Scheme 9. ...