Tetrahedron

Mechanochemistry of some hydrocarbons

LD Field, S Sternhell, HV Wilton

文献索引：Field, Leslie D.; Sternhell, Sever; Wilton, Howard V. Tetrahedron, 1997 , vol. 53, # 11 p. 4051 - 4062

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被引用次数: 44

摘要

Aromatic hydrocarbons (biphenyl, naphthalene, anthracene and phenanthrene) were subjected to ball milling (SPEX® 8000) with approximately ten-fold weight of inorganic materials (alumina or silica). After about 24 h all of the hydrocarbons were converted largely to carbon (graphite), but at intermediate stages disproportionation products (tetralin, phenylcyclohexane, bicyclohexyl, 9, 10-dihydroanthracene, 1, 2, 3, 4- ...