Synthesis of isothiocyanates from non-aromatic nitrogen-containing heterocycles

J Gonda, P Kristian, Ľ Mikler

文献索引：Gonda, Jozef; Kristian, Pavol; Mikler, Lubomir Collection of Czechoslovak Chemical Communications, 1986 , vol. 51, # 1 p. 112 - 117

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被引用次数: 4

摘要

Abstract Investigation of the reaction of thiophosgene with Δ 2-oxazolines I, Δ 3-thiazolines II, 4H-benzo [d][1, 3] thiazines III, 2-methoxypentahydro-Δ 1-azepine IV, theophylline and caffeine showed that only compounds I and IV reacted to give 2-acyloxyethyl isothiocyanates and methyl 6-isothiocyanatohexanoate. The structure of these products was corroborated by IR, 1 H NMR, 13 C NMR and mass spectral methods. The suitability of the ...