Reactions of Aldoxime Derivatives with Bases. I. The Reactions of Certain Acetyl-β-aldoximes with Alkali1

CR Hauser, CT Sullivan

文献索引：Hauser; Sullivan Journal of the American Chemical Society, 1933 , vol. 55, p. 4611

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被引用次数: 4

摘要

It seems to be rather generally agreed that when the acetyl derivatives of two geometrically isomeric aldoximes react with alkali, the@-isomer forms the nitrile, 2 and the a-isomer, the original oxime. Recently, however, Brady and McHugh3 have isolated the corresponding j3- oxime in addition to the nitrile from the reaction products of certain acetyl aldoximes and 2 N sodium hydroxide. They state,“The isolation of the/3-aldoxime by treating with cold sodium ...