Tetrahedron

Rhenium complex-catalyzed acylative cleavage of ethers with acyl chlorides

…, T Nishimura, K Kaiba, T Tanaka, Y Takahashi…

文献索引：Umeda, Rui; Nishimura, Takashi; Kaiba, Kenta; Tanaka, Toshimasa; Takahashi, Yuuki; Nishiyama, Yutaka Tetrahedron, 2011 , vol. 67, # 38 p. 7217 - 7221

全文：HTML全文

被引用次数: 12

摘要

It was found that rhenium complex was an efficient catalyst for the acylative cleavage of C–O bond of ethers with acyl chlorides. When acyclic ethers were allowed to react with acyl chlorides in the presence of a catalytic amount of ReBr (CO) 5, acylative cleavage of C–O bond of acyclic ethers smoothly proceeded to give the corresponding esters in moderate to good yields. Similarly, cyclic ethers were acylative cleaved by acyl chlorides to give the ...