Preparation of samarium (II) iodide: quantitative evaluation of the effect of water, oxygen, and peroxide content, preparative methods, and the activation of samarium …
M Szostak, M Spain, DJ Procter
文献索引:Szostak, Michal; Spain, Malcolm; Procter, David J. Journal of Organic Chemistry, 2012 , vol. 77, # 7 p. 3049 - 3059
Samarium (II) iodide (SmI2) is one of the most important reducing agents in organic synthesis. Synthetic chemistry promoted by SmI2 depends on the efficient and reliable preparation of the reagent. Unfortunately, users can experience difficulties preparing the reagent, and this has prevented realization of the full synthetic potential of SmI2. To provide synthetic chemists with general and reliable methods for the preparation of SmI2, a ...