Practical First Total Synthesis of the Potent Phytotoxic (±)??Naphthotectone, Isolated from Tectona grandis

…, CKZ Andrade, JMG Molinillo…

文献索引：Guerrero-Vasquez, Guillermo A.; Andrade, Carlos Kleber Z.; Molinillo, Jose M. G.; MacIas, Francisco A. European Journal of Organic Chemistry, 2013 , # 27 p. 6175 - 6180

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被引用次数: 4

摘要

Abstract Naphthotectone is a quinone isolated recently from teak extracts of Tectona grandis. It has been shown to be one of the most abundant compounds and the most active compound isolated form teak. Thus, it has been proposed that naphthotectone is one of the compounds responsible for the allelophathic activity of this plant. An efficient total synthesis of (±)-naphthotectone was achieved in seven steps and 31% overall yield. The best ...