Organosilicon compounds. LXXIV. The effect of structure on the basicity of some dimethylaminosilanes

Z Pacl, M Jakoubkova, Z Papoušková…

文献索引：Pacl,Z. et al. Collection of Czechoslovak Chemical Communications, 1971 , vol. 36, p. 1588 - 1597

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被引用次数: 16

摘要

A series of dimethylaminosilanes of the types (C2 Hs) 4 _ nSi [N (CH3hln and RR3 _ nSi [N (CH3hln (11= 1-4, R= CHz= CH-, p-(CH3hHSiC6Hs--, Hand R'= CH3- and C2 Hs-) was prepared. The relative basicities of the nitrogen atoms in these compounds were determined by infrared spectroscopy. The~ v values of the hydrogen bonds of deuteriochloroform (pyrrole) with the dimethylaminosilanes studied are interpreted in terms of a (p->-d) n; ...