Highly efficient “click” functionalization of poly (3-azidopropyl methacrylate) prepared by ATRP

BS Sumerlin, NV Tsarevsky, G Louche, RY Lee…

文献索引：Tsarevsky, Nicolay V.; Sumerlin, Brent S.; Matyjaszewski, Krzysztof Macromolecules, 2005 , vol. 38, # 9 p. 3558 - 3561

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被引用次数: 424

摘要

To prepare polymers with pendant functionality capable of participating in highly efficient CuI- catalyzed 1, 3-dipolar cycloaddition of azide and alkynes, monomers with acetylene or azido groups were polymerized via controlled radical polymerization. Atom transfer radical polymerization (ATRP) of propargyl methacrylate (PgMA) resulted in high polydispersities (M w/M n> 3), multimodal molecular weight distributions, and cross-linked networks at ...