Novel [3+ 2] Photocycloadditions of 3-(1-Alkynyl)-2-cycloalken-1-ones with Alkenes

HJ Rathjen, P Margaretha, S Wolff…

文献索引：Rathjen; Margaretha, Paul; Wolff, Steven; Agosta, William C. Journal of the American Chemical Society, 1991 , vol. 113, # 10 p. 3904 - 3909

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被引用次数: 25

摘要

Abstract: Photochemical cycloaddition of 3-alkynylcycloalkenones 3a, h, c and 4 with tetramethylethylene (8) at-40 OC leads to mixtures of 1: 1 adducts that arise largely from 1, 5 closure of the biradical intermediate (eq l), providing examples of a novel [3+ 21 cycloaddition reaction. Similar reactions occur between these same ketones and l, l- dimethoxy-2-methylpropene (9) and 1, I-dimethoxyethylene (10). In several cases, these ...