Synthèse d'aryl nitronorbornènes par cycloaddition de Diels-Alder entre les aryl-nitroéthylènes et le cyclopentadiène. Justification de la stéréochimie et de la …
J Bourguignon, GL Nard…
文献索引：Bourguignon, Jean; Le Nard, Gilles; Queguiner, Guy Canadian Journal of Chemistry, 1985 , vol. 63, p. 2354 - 2361
Syntheses of numerous 2-aryl nitroethylenes (nitrostyrenes) have been optimized. The nitrostyrenes have been reacted with cyclopentadiene in Diels-Alder cycloadditions and the 3-aryl 2-nitronorbornenes obtained have been reduced into 3-aryl 2-aminonorbornenes. These compounds are potentially dopaminergic molecules. The stereochemistry of the adducts obtained in the Diels-Alder reaction has been determined by 1H nmr. The ...
