Journal of Fluorine Chemistry

Preparation, stability, reactivity and synthetic utility of a cadmium stabilized complex of difluoromethylene phosphonic acid ester

DJ Burton, R Takei, S Shin-Ya

文献索引：Burton, Donald J.; Takei, Ryutaro; Shin-Ya, Seiji Journal of Fluorine Chemistry, 1981 , vol. 18, p. 197 - 202

被引用次数: 46

摘要

Abstract Diethyl bromodifluoromethyl phosphonate reacts readily with cadmium metal to form a stable cadmium complex. Depending on solvent, this functionalized organocadmium reagent exhibits stability for days to months. It reacts with a variety of electrophiles and serves as a synthetically useful source for the introduction of the difluoromethylene phosphonate group into organic compounds.

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