Organometallics

Charge-transfer spectra of permethylated polygermanes-TCNE to afford 1: 1 adducts

K Mochida, C Hodota, R Hata, S Fukuzumi

文献索引：Mochida, Kunio; Hodota, Chikako; Hata, Rieko; Fukuzumi, Shunichi Organometallics, 1993 , vol. 12, p. 586 - 588

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被引用次数: 42

摘要

Summary: Charge-transfer spectra of permethylated polygermane-tetracyanoethylene (TCNE) complexes were observed. The frequency of charge-transfer spectra was linearly related to ionization potentials (or electrochemical oxidation potentials) of the polygermanes. Polygermanes inserted into TCNE to afford 1: 1 adducts under mild conditions.