Predicting the photoinduced electron transfer thermodynamics in polyfluorinated 1, 3, 5-triarylpyrazolines based on multiple linear free energy relationships
M Verma, AF Chaudhry, CJ Fahrni
文献索引：Verma, Manjusha; Chaudhry, Aneese F.; Fahrni, Christoph J. Organic and Biomolecular Chemistry, 2009 , vol. 7, # 8 p. 1536 - 1546
The photophysical properties of 1, 3, 5-triarylpyrazolines are strongly influenced by the nature and position of substituents attached to the aryl-rings, rendering this fluorophore platform well suited for the design of fluorescent probes utilizing a photoinduced electron transfer (PET) switching mechanism. To explore the tunability of two key parameters that govern the PET thermodynamics, the excited state energy ΔE00 and the acceptor ...
