Electrophilic versus free radical reactions of halogens and halogen systems with perfluoroalkenes and a perfluoroalkylethylene
…, MJ Bostic, EA Miller, CM O'Neill, BJ Powers…
文献索引：Shellhamer, Dale F.; Allen, Jeannette L.; Allen, Rachel D.; Bostic, Melissa J.; Miller, Elizabeth A.; O'Neill, Colleen M.; Powers, Benjamin J.; Price, Eric A.; Probst, John W.; Heasley, Victor L. Journal of Fluorine Chemistry, 2000 , vol. 106, # 1 p. 103 - 112
Ionic and free radical addition of halogen systems were carried out with perfluoroheptene-1 (1), octafluorocyclopentene (2), 1H, 1H, 2H-perfluorooctene-1 (3) and perfluoro-4-methyl-2- pentene (4). The terminal alkene 1 was treated with chlorine in tert-butyl alcohol as solvent with mercury catalyst under reaction conditions that assure an ionic pathway. Bromine did not react with 1 under similar conditions. Chlorine monofluoride reacts with 1 in methylene ...
