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Tunable Fluorene??Based Dynamers through Constitutional Dynamic Chemistry

N Giuseppone, G Fuks, JM Lehn

文献索引:Giuseppone, Nicolas; Fuks, Gad; Lehn, Jean-Marie Chemistry - A European Journal, 2006 , vol. 12, # 6 p. 1723 - 1735

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被引用次数: 89

摘要

Abstract Dynamic covalent iminofluorene-based oligomers and polymers have been generated. They undergo constitutional recomposition under the effect of two parameters, acidity and Zn II metal ions. As a result, marked changes in physical properties take place. The results illustrate the response of such a dynamic system to chemical effectors (H+ and Zn II), thus demonstrating the adaptive behavior of the system under the pressure of ...