Synthesis and Structure of Boron–Bithiazole Complexes

M Findlater, NS Swisher…

文献索引：Findlater, Michael; Swisher, Nicholas S.; White, Peter S. European Journal of Inorganic Chemistry, 2010 , # 34 p. 5379 - 5382

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被引用次数: 2

摘要

Abstract The syntheses of the first reported p-block complexes of the bithiazole moiety are reported, namely [(tBuBTz) BBr 2][Br](3), and [(PhBTz) BBr 2][Br](4)(tBuBTz= 4, 4′-di-tert- butyl-2, 2′-bithiazole and PhBTz= 4, 4′-diphenyl-2, 2′-bithiazole). Compounds 3 and 4 were prepared via reaction of equimolar quantities of the appropriate bithiazole ligand with BBr 3. The molecular structures of 3, and the known compound PhBTz (2) were ...