The Journal of Organic Chemistry

The Asinger reaction with 1-methyl-4-piperidone

RE Lyle, R Munk, L Ladd

文献索引：Lyle,R.E. et al. Journal of Organic Chemistry, 1965 , vol. 30, p. 293 - 294

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被引用次数: 4

摘要

methyl-4-piperidone (1). The successful reduction of thiamine chloride'and numerous imines* with complex metal hydrides led to a study of these reductions with 2a. Sodium borohydride gave no reaction. Lithium aluminum hydride caused reduction of the double bond, but hydrogenolysis of the thiazolidine ring may have occurred in a manner similar to that described by Eliel and co-workersg to give 4. Since the product of this reaction was ...