Journal of Organometallic Chemistry

Silipramine and related derivatives

JY Corey, RL Farrell

文献索引：Corey,J.Y.; Farrell,R.L. Journal of Organometallic Chemistry, 1978 , vol. 153, p. 15 - 23

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被引用次数: 15

摘要

Abstract A series of new 10, 11-dihydro-5H-dibenzo [b, f] silepins are prepared from the reaction o, o′-dilithiobibenzyl with the chlorosilanes HSiCl 3, ClCH 2 CH 2 CH 2 SiCl 3, MeSiHCl 2 and MeSi (CH 2 CH 2 CH 2 Br) Cl 2. The only isolated silepin product produced from HSiCl 3 is the spiro derivative. The silepin product produced from MeSiHCl 2 reacts with N, N-dimethylallylamine in the presence of H 2 PtCl 6 to give silipramine, a tricyclic ...