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Journal of the American Chemical Society

Stereochemistry and Mechanism of Silane Additions to Olefins. II. Chloroplatinic Acid-catalyzed Addition of Trichlorosilane to Alkylcyclohexenes

TG Selin, R West

文献索引:Selin,T.G.; West,R. Journal of the American Chemical Society, 1962 , vol. 84, p. 1863 - 1868

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被引用次数: 31

摘要

Thc addition IJf triclilorosilaiie t (ia iiuniber of alkglcyclohexenes was examined using chloroplatiiiic acid as it catalyst. Terniinal adducts were obtained exclusively with 4- methylcyclohexene, 1-metliylcyclohexene and 1-ethylcyclohexetie. The addition to 4- methylcyclohexene proceeded through rearrangement to 1-metliylcyclohexene. Both 1-n- propylcyclohesene and 1-n-octylcyclohexene were unreactive under the same conditions. ...