Dicoordinated 2H-phospholes as transient intermediates in the reactions of tervalent phospholes at high temperature. One-step syntheses of 1- …
F Mathey, F Mercier, C Charrier, J Fischer…
文献索引：Mathey, Francois; Mercier, Francois; Charrier, Claude; Fischer, Jean; Mitschler, Andre Journal of the American Chemical Society, 1981 , vol. 103, # 15 p. 4595 - 4597
The identity of fluoride-containing products was established by 19F NMR spectroscopy (Figure 2). The glyoxalase I only reaction gave a sharp singlet for fluoride ion as expected. The glyoxalase I and I1 reaction afforded, in addition to the fluoride ion singlet, a proton- coupled sextet (J~ H, F= 47, JH, F= 30 Hz) identical with authentic fluorolactate. This product eluted with fluorolactate from a Dowex 1 (formate; 0-6 M formic acid) column, and ...
