The Journal of Organic Chemistry

Thermal decomposition of methyl and phenyl triphenylmethylazocarboxylates

DE Zabel, WS Trahanovsky

文献索引：Zabel,D.E.; Trahanovsky,W.S. Journal of Organic Chemistry, 1972 , vol. 37, # 15 p. 2413 - 2418

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被引用次数: 9

摘要

Products from the decomposition of methyl and phenyl triphenylmethylazocarboxylates at 60'in benzene or cumene are reported. These and other results indicate that these trjtylazocarboxylates decompose to trityl radicals, nitrogen, and the corresponding alkoxycarbonyl radicals (ROC= O) which can escape from a solvent cage and couple with other radicals before decarboxylating or decarbonylating. These alkoxycarbonyl radicals ...