PdCl 2 (py) 2 encaged in monodispersed zeolitic hollow spheres: a highly efficient and reusable catalyst for Suzuki–Miyaura cross-coupling reaction in aqueous …
Z Guan, J Hu, Y Gu, H Zhang, G Li, T Li
文献索引:Guan, Zhenhong; Hu, Jianglin; Gu, Yanlong; Zhang, Haojun; Li, Guangxing; Li, Tao Green Chemistry, 2012 , vol. 14, # 7 p. 1964 - 1970
By encaging the PdCl2 (py) 2 complex (py= pyridine) in the interior space of silicalite-1 hollow spheres (SHS), a novel solid palladium catalyst, PdCl2 (py) 2@ SHS, was successfully prepared. The structure and composition of the solid catalyst was characterized by SEM, TEM, XRD, N2 sorption, FT-IR and XPS. This catalyst afforded fast conversions for the Suzuki–Miyaura cross-coupling reactions of various aryl halides and arylboronic acids ...