Organometallics

Cis-and trans-(4-alkylcyclohexyl) stannanes. Isomers for stereochemical studies of substitution at saturated carbon-tin bonds

HA Olszowy, W Kitching

文献索引：Olszowy, Henry A.; Kitching, William Organometallics, 1984 , vol. 3, p. 1670 - 1675

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被引用次数: 5

摘要

The synthesis and characterization of pure cis-and trans-(4-methylcyclohexyl)-and cis-and trans-(4-tert-butylcyclohexyl) triphenylstannanes are described. Their conversion, by hydrochloric acid induced dephenylation-isopropylation, to the corresponding triisopropylstannanes proceeds smoothly to provide stereoisomers capable of providing significant information with respect to brominolysis and trifluoroacetolysis of the carbon-tin ...