J. Am. Chem. Soc

Controlled orientation of polyconjugated guest molecules in tunable host cavities

AC Soegiarto, A Comotti, MD Ward

文献索引：Soegiarto, Airon C.; Comotti, Angiolina; Ward, Michael D. Journal of the American Chemical Society, 2010 , vol. 132, # 41 p. 14603 - 14616

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被引用次数: 41

摘要

Abstract: Linear conjugated guest molecules with high aspect ratios form inclusion compounds with guanidinium organodisulfonate (GDS) host frameworks in which organodisulfonate “pillars” connect opposing GS sheets to generate lamellar architectures that reflect templating by the guest. Through judicious selection of pillars having adjustable lengths (lS-S, as measured by the separation between distal sulfur atoms) and guests of ...