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Spectrophotometric investigations of the role of the organic solvent on the acid dissociation constants of some azo dyes derived from 2-aminobenzothiazole

YH Ebead, HMA Salman, M Khodari…

文献索引:Ebead; Salman; Khodari; Ahmed Journal of Molecular Liquids, 2010 , vol. 154, # 1 p. 52 - 57

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被引用次数: 9

摘要

Proton dissociation constants (pKa) of a set of hydroxyl azo dyes in various organic solvent+ water mixtures have been determined. The results obtained were discussed in terms of the solvent characteristic. Effects of hydrogen-bonding interactions and solvent basicity on the ionization process have been also discussed. In a nutshell, the pKa values of the investigated compounds were found to be largely depending on both the ratio and the ...