Reaction of Tricoordinate Phosphorus Compounds with Pseudohalogens. Scope and Mechanism

A Skowrońska, E Krawczyk, J Burski

文献索引：Skowronska, Aleksandra; Krawczyk, Ewa; Burski, Janusz Phosphorus and Sulfur and the Related Elements, 1983 , vol. 18, p. 233 - 236

全文：HTML全文

被引用次数: 14

摘要

Abstract The selectivity of sulphur, selenium and oxygen removal from pseudohalogens: phosphorus disulphides 1 and 2, diselenides 3 and oxophosphoranesulphenyl chlorides 4 has been investigated. A mechanistic rationalization is proposed to account for sulphur (selenium)/oxygen extrusion variation as a function of substrates structure and reaction conditions.