Tetrahedron

New synthesis of 4-acetoxy-2-azetidinones by use of electrochemical oxidation

M Mori, K Kagechika, H Sasai, M Shibasaki

文献索引：Mori, Miwako; Kagechika, Katsuji; Sasai, Hiroaki; Shibasaki, Masakatsu Tetrahedron, 1991 ,  vol. 47,  # 4/5  p. 531 - 540

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被引用次数: 39

摘要

4-Acetoxy-2-azetidinone was synthesized from 4-carboxy-2-azetidinone by Kolbe-type electrolysis. Optically pure 4-acetoxy-3-[1-(t-butyldimethylsiloxy) ethyl]-2-azetidinone, which is an important intermediate for the synthesis of thienamycin, and (+)-PS-5 were synthesized by use of this method.