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Catalytic deoxygenation of oleic acid in continuous gas flow for the production of diesel-like hydrocarbons

M Arend, T Nonnen, WF Hoelderich, J Fischer…

文献索引:Arend, Matthias; Nonnen, Thomas; Hoelderich, Wolfgang F.; Fischer, Juergen; Groos, Jeremie Applied Catalysis A: General, 2011 , vol. 399, # 1-2 p. 198 - 204

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被引用次数: 41

摘要

Abstract Continuous gas phase deoxygenation of oleic acid in the presence of hydrogen employing a granular 2 wt% Pd/C catalyst was investigated under solvent free conditions. Conversion of oleic acid and selectivity to the desired diesel-like C17 hydrocarbons heptadecane and heptadecenes was studied at different reaction conditions such as temperature, gas flow and catalyst amount. The best hydrocarbon yield was achieved with ...