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Carbohydrate research

Synthesis of methyl shikimate from methyl (1, 3, 4/2, 5)-2, 3, 4, 5-tetrahydroxycyclohexane-1-carboxylate

S Ogawa, Y Aoki, T Takagaki

文献索引:Ogawa, Seiichiro; Aoki, Yasuyuki; Takagaki, Tohei Carbohydrate Research, 1987 ,  vol. 164, p. 499 - 505

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被引用次数: 8

摘要

Fig. 1. The compounds described here are named and numbered according to the IUPAC- IUB 1973 Recommendations for Cyclitols (ref. 2). Thus Cl is the reference carbon for determining configurational series (L), except in 1, 2-unsaturated compounds, where the rcfercnce carbon is C-3. For convenience, only single enantiomers corresponding IO methyl r.-shikimate are depicted. hexene-1-carboxylate'(DL-4) with hydrogen peroxide and formic ...