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Alkaline polymerization of 6-caprolactam. XXII. Preparation and properties of some N-alkylacetoacetamides and their hydrolysis in acid and alkaline media

Z Bukač, J Šebenda

文献索引:Bukac,Z.; Sebenda,J. Collection of Czechoslovak Chemical Communications, 1966 , vol. 31, p. 3315 - 3330

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被引用次数: 12

摘要

Several N-alkylacetoacetamides have been prepared as model compounds representing some of the possible products from the disappearing catalytic system in the alkaline polymerization of caprolactam, and their physical and chemical properties have been determined. With N-ethylacetoamide the effect of pH of the medium on hydrolysis was studied at 130 C and the catalytic constants of the acid and the alkaline hydrolysis were ...