Australian Journal of Chemistry

Synthetic applications of intramolecular insertion in arylcarbenes. V o-Benzyl, phenylamino, phenoxy and phenylthio phenylcarbenes

WD Crow, H McNab

文献索引：Crow, Wilfrid D.; McNab, Hamish Australian Journal of Chemistry, 1981 , vol. 34, # 5 p. 1037 - 1050

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被引用次数: 5

摘要

Abstract The 2-(XC 6 H 4)-substituted phenylcarbenes in which X= CH 2, NH, O and S have been generated and pyrolysed in the gas phase at low pressure. When X= CH 2 or NH, the main reaction is simple insertion into the adjacent o-position of the XC 6 H 5 ring to give