Syntheses and Properties of New Liquid-Crystalline Polymers Having 1, 3, 2-Dioxaborinane Pendants.
H Matsubara, K Seto, H Tabuchi, H Imazaki…
文献索引:Matsubara, Hiroshi; Seto, Koji; Tabuchi, Hitoshi; Imazaki, Hideyuki; Takahashi, Shigetoshi Bulletin of the Chemical Society of Japan, 1993 , vol. 66, # 2 p. 578 - 584
Polyacrylates and polymethacrylates having various 1, 3, 2-dioxaborinane derivatives as pendants have been synthesized and demonstrated to form chiral smectic C and/or smectic A phases which are more stable than those formed by the corresponding monomes. They provide a new family of chiral liquid crystalline side-chain polymers containing boron atoms in the pendant group.