PHOSPHORDERIVATE DES E-1, 1, 1, 5, 5, 5-HEXAFLUOR-4-TRIMETHYLSILOXY-3-PENTEN-2-ONS

R Francke, GV Röschenthaler

文献索引：Francke, Rudolph; Roeschenthaler, Gerd-Volker Phosphorus and Sulfur and the Related Elements, 1988 , vol. 36, p. 125 - 128

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被引用次数: 7

摘要

Abstract Silylated phosphites (RO) 2POSiMe3 and E-1, 1, 1, 5, 5, 5-hexafluoro-4- trimethylsiloxy-3-pentene-2-one reacted to give the chiral phosphonates E-(RO) 2P (O) C (CF3)(OSiMe3) CH [dbnd] C (OSiMe3) CF3 (R= Me, Et. Ph, SiMe3). Die silylierten Phosphite (RO) 2POSiMe3 und E-1, 1, 1, 5, 5, 5-Hexafluor-4-trimethylsiloxy-3-penten-2-on ergaben die chiralen Phosphonate E-(RO) 2P (O) C (CF3)(OSiMe3) CH [dbnd] C (OsiMe3) CF3 (R= ...