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Journal of Inorganic and Nuclear Chemistry

Cyclopentadienyl-triethylphosphine-copper (I) and bis-cyclopentadienylmercury (II)

G Wilkinson, TS Piper

文献索引:Journal of Inorganic and Nuclear Chemistry, , vol. 2, p. 32,34

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被引用次数: 97

摘要

J. Inorganic and Nuclear Chemistry 1956. ... Since the normal structure of the cuprous state is 3d10 , one of the d-orbitals would have to be freed in order to form a "sandwich bond" to copper(I). While rigorous chemical proof that the copper-ring bond is not of the "sandwich ...