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Simple and efficient method for the oxidation of sulfides to sulfoxides: application to the preparation of glycosyl sulfoxides

R Kakarla, RG Dulina, NT Hatzenbuhler…

文献索引:Kakarla, Ramesh; Dulina, Richard G.; Hatzenbuhler, Nicole T.; Hui; Sofia, Michael J. Journal of Organic Chemistry, 1996 ,  vol. 61,  # 23  p. 8347 - 8349

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被引用次数: 71

摘要

Compounds containing a sulfoxide moiety are useful synthetic intermediates for the construction of various chemically and biologically significant molecules. 1 The discovery by Kahne and co-workers2 of the anomeric glycosyl sulfoxide as a novel glycosyl donor provided a new and powerful method for chemical glycosylation. Synthesis of a wide range of glycosides3 and oligosaccharides4 have been reported using the Kahne sulfoxide ...