Abstract The syntheses and structure of 2-triarylphosphoranimine-1, 2, 3-triazole derivatives from vicinal diazides have been investigated. Compounds derived from dichloronapththoquinone, 2, 3-dichloro-5, 6-dimethylbenzoquinone, and 2, 3, 5, 6- tetrachlorobenzoquinone are included. X-ray structures, NMR, IR, UV, and cyclic voltammetry data are reported. Compound 2 crystallizes in space group P ̄ 1 with a= ...