Metal π-complexes of cyclooctatetraenes: V. Synthesis and x-ray analysis of tetrameric dibenzo [a, e] cyclooctatetraenecopper (1) chloride, a new “step” configuration …

TCW Mak, HNC Wong, KH Sze, L Book

文献索引：Mak, Thomas C.W.; Wong, Henry N.C.; Sze, Kong Hung; Book, Langford Journal of Organometallic Chemistry, 1983 ,  vol. 255,  # 1  p. 123 - 134

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被引用次数: 15

摘要

Tetrameric dibenzo[a,e]cyclooctatetraenecopper(I), 3 [(C 16 H 12 )CuCl] 4 , 1, has been synthesized and characterized by X-ray crystallography. Complex 1 crystallizes in space group P with a 9.287(7), b 10.818(7), c 13.234(5) Å, α 91.34(4), β 103.44(4), γ 95.20(5)°, V 1287(1) Å 3 , and Z = 1. The structure has been refined to R F = 0.063 and R wF = 0.078 for 3286 observed Mo-K α data and 325 variables. The cyclic molecule, which has crystallographically ...