Synthesis of a family of triarylphosphanes with fluorous phase affinity

D Sinou, D Maillard, G Pozzi

文献索引：Sinou, Denis; Maillard, David; Pozzi, Gianluca European Journal of Organic Chemistry, 2002 , # 2 p. 269 - 275

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被引用次数: 21

摘要

Abstract A very efficient synthesis of new perfluoro-functionalized triarylphosphanes using an oxygen substituent as the branching point for the introduction of the perfluoro chain has been developed. This approach enabled the introduction of the perfluoro tail at the para, meta, and ortho position, giving highly perfluorinated analogues of triphenylphosphane containing between 54 and 59 wt% fluorine. This methodology has been extended to the ...