Tetrahedron Letters

Carbon–carbon bond fission on oxidation of primary alcohols to carboxylic acids

AV Bekish

文献索引：Bekish, Andrei V. Tetrahedron Letters, 2012 , vol. 53, # 24 p. 3082 - 3085

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被引用次数: 5

摘要

α-Carbon–carbon bond cleavage is shown to be a general side reaction accompanying the oxidation of unbranched primary alcohols to the corresponding carboxylic acids using HNO3, CrO3/H2SO4/H2O/acetone, CrO3/CH3COOH, PDC/DMF, H5IO6/CrO3, KMnO4/H+,