Beiträge zur chemie des iodpentafluorids Teil V. IF5 als oxidatives fluorierungsmittel für elementorganika des arsens, antimons und bismuts: selektivität und …
HJ Frohn, H Maurer
文献索引：Frohn,H.J.; Maurer,H. Journal of Fluorine Chemistry, 1986 , vol. 34, p. 129
Zusammenfassung The reactions of organometallic compounds R 3 E, R 2 ECl, and RECl 2 (R= C 6 F 5, C 6 H 5, p-FC 6 H 4, p-CF 3 C 6 H 4, and n-Bu, E= As, Sb, and Bi) with IF 5 are studied. While triaryl-and trialkylarsines and stibines can be transformed into the corresponding arsoranes and stiboranes in good yields bismuthines show different types of products depending on the organic group: a) oxidation to difluorobismuthoranes, b) ...
