New modes of reactivity in the threshold of the reduction potential in solution. Alkylation of lithium PAH (polycyclic aromatic hydrocarbon) dianions by primary …
C Melero, RP Herrera, A Guijarro…
文献索引：Melero, Cristobal; Herrera, Raquel P.; Guijarro, Albert; Yus, Miguel Chemistry - A European Journal, 2007 , vol. 13, # 36 p. 10096 - 10107
Abstract Some of the most highly reduced organic species in solution, such as the dianions of PAHs (polycyclic aromatic hydrocarbons) display unexpected reactivity patterns when they react with an appropriate counterpart. As seen before in their reaction with propene and other alkenes, PAHs− 2 apparently react with fluoroalkanes in a nucleophilic fashion in spite of being generally regarded as powerful electron-transfer reagents in their reactions with ...
