The Journal of Organic Chemistry

Electroorganic chemistry. 68. A new method of 1, 4-transposition of a carbonyl group

T Shono, S Kashimura

文献索引：Shono, Tatsuya; Kashimura, Shigenori Journal of Organic Chemistry, 1983 , vol. 48, # 11 p. 1939 - 1940

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被引用次数: 10

摘要

It is shown in the present study that a novel method for carrying out the transposition of a carbonyl group to the y-position (1,l-transposition, n = 3) is successfully achievable by using anodic oxidation of dienol acetates as a key reaction. The whole reaction process is shown in Scheme I, in which the transformation of 2 and 6 is described in the present st ~ dy . ~ ? ~ The anodic acetoxylation or methoxylation of carbonyl compounds at the a-position has been shown in the pre- ...