Functionalization of Non??activated C H Bonds of Alkanes: An Effective and Recyclable Catalytic System Based on Fluorinated Silver Catalysts and Solvents

…, L Vendier, A Caballero, M Etienne…

文献索引：Fuentes, M. Angeles; Munoz, Bianca K.; Jacob, Kane; Vendier, Laure; Caballero, Ana; Etienne, Michel; Perez, Pedro J. Chemistry - A European Journal, 2013 , vol. 19, # 4 p. 1327 - 1334

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被引用次数: 19

摘要

Abstract The complexes F n-Tp math image Ag (L)(F n-Tp math image= a perfluorinated hydrotris (indazolyl) borate ligand; L= acetone or tetrahydrofuran) efficiently catalyze the functionalization of non-activated alkanes such as hexane, 2, 3-dimethylbutane, or 2- methylpentane by insertion of CHCO 2 Et units (from N 2 CHCO 2 Et, ethyl diazoacetate, EDA) into their C [BOND] H bonds. The reactions are quantitative (EDA-based), with no ...