Tetrahedron

Photochemistry of glycosyl azides-II11For Part I, see Ref. 1.: Investigation of the dual behavior: formation of a reversible intermediate and chain-degradation

WA Szarek, O Achmatowicz, J Plenkiewicz…

文献索引：Szarek,W.A. et al. Tetrahedron, 1978 , vol. 34, p. 1427 - 1433

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被引用次数: 32

摘要

The photochemistry of glycosyl azides has been studied. Some of the azides, for example, β- d-glucopyranosyl or α-d-mannopyranosyl azide, were found to afford in good yield, on irradiation with UV light, the corresponding next-lower aldose. In other cases, for example, β- maltosyl or β-d-ribofuranosyl azide, there was observed the formation of an intermediate which, on standing in the dark, reverts back to starting material. A rationalization of the two ...