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A double arene hydroxylation mediated by dicopper (II)-hydroperoxide species

…, M Gullotti, R Dillinger, C Näther, F Tuczek

文献索引:Battaini, Giuseppe; Monzani, Enrico; Perotti, Angelo; Para, Cristina; Casella, Luigi; Santagostini, Laura; Gullotti, Michele; Dillinger, Renee; Naether, Christian; Tuczek, Felix Journal of the American Chemical Society, 2003 , vol. 125, # 14 p. 4185 - 4198

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被引用次数: 47

摘要

The dicopper (II) complex [Cu2 (L)] 4+(L= α, α'-bis {bis [2-(1'-methyl-2'-benzimidazolyl) ethyl] amino}-m-xylene) reacts with hydrogen peroxide to give the dicopper (II)-hydroquinone complex in which the xylyl ring of the ligand has undergone a double hydroxylation reaction at ring positions 2 and 5. The dihydroxylated ligand 2, 6-bis ({bis [2-(3-methyl-1 H- benzimidazol-2-yl) ethyl] amino} methyl) benzene-1, 4-diol was isolated by decomposition ...