The Journal of Organic Chemistry

Reaction of Enol Ethers with Carbenes. VII. 1 Substituted Allyl Sulfides2

WE Parham, SH Groen

文献索引：Parham,W.E.; Groen,S.H. Journal of Organic Chemistry, 1966 , vol. 31, p. 1694 - 1698

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被引用次数: 24

摘要

The thiolester 19 was characterized by its spectra (nmr and infrared) and by hydrolysis with aqueous so-dium hydroxide to 2, 2-dimethyl-3-butenoic acid (20). The acid 20 was converted to the solid dibromide 21. The carbene reaction was repeated using 7, y- dimethylallyl ethyl sulfide and similar results were obtained (see Experimental Section). a, a- Dimethylallyl ethyl sulfide (15) was prepared according to Scheme I11 which was ...