A new class of silatranes N [CH2 (Me2C6H2) O] 3SiR was prepared by the reaction of organosilanes with tris (2-hydroxy-4, 6-dimethylbenzyl) amine (5) in the case of 1, 3, and 4, and by the reaction of Si (OMe) 4 with the same amine (5) to give 2. This is the first series of silatranes containing all six-membered rings. Their structures were established by X-ray analysis and correlated with 29Si NMR data. VT 1H NMR spectra reflected fluxional ...
[Bull, Steven D.; Davidson, Matthew G.; Johnson, Andrew L.; Mahon, Mary F.; Robinson, Diane E. J. E. Chemistry - An Asian Journal, 2010 , vol. 5, # 3 p. 612 - 620]
[Johnson, Andrew L.; Davidson, Matthew G.; Perez, Yolanda; Jones, Matthew D.; Merle, Nicolas; Raithby, Paul R.; Richards, Stephen P. Dalton Transactions, 2009 , # 28 p. 5551 - 5558]
![2-[[bis[(2-hydroxy-3,5-dimethylphenyl)methyl]amino]methyl]-4,6-dimethylphenol结构式](https://image.chemsrc.com/caspic/210/57914-22-4.png)