A gas kinetic study of the pyrolysis of octamethyl-1, 2-disilacyclobutane

IMT Davidson, NA Ostah, D Seyferth…

文献索引：Davidson, Iain M. T.; Ostah, Naaman A.; Seyferth, Dietmar; Duncan, Don P. Journal of Organometallic Chemistry, 1980 , vol. 187, # 3 p. 297 - 304

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摘要

Abstract Pyrolysis of octamethyl-1, 2-disilacyclobutane (I) has been shown to proceed by a unimolecular isomerisation involving a biradical which undergoes internal hydrogen- abstraction. Kinetic data were obtained for this pyrolysis and for that of the oxidation product of I, octamethyl-1, 3-disila-2-oxacyclopentane (II). A few additional experiments indicated that intermediates with π-bonds to silicon may be generated by photolysis of I. The ...